DISC ONE
Episodes:
- "The Mysterons"
- "Winged Assassin"
- "Big Ben Strikes Again"
- "Point 783"
- "Manhunt"
- "Operation Time"
- "Renegade Rocket"
- "White As Snow"
Audio Commentary by co-creator/co-writer/executive producer Gerry Anderson on "The Mysterons" (2001)
"Introduction to Captain Scarlet" text
Photo Gallery
DVD Production Credits

DISC TWO
Episodes:
- "Seek and Destroy"
- "Spectrum Strikes Back"
- "Avalanche"
- "Shadow of Fear"
- "The Heart of New York"
- "Fire at Rig 15"
- "The Launching"
- "Lunarville 7"
Character Biographies:
- Captain Scarlet
- Captain Blue
- Captain Black
- Colonel White
- Lieutenant Green
- Captain Ochre
- Captain Magenta
Gerry Anderson Biography & Filmography
Photo Gallery
Production Gallery
DVD Production Credits

DISC THREE
Episodes:
- "The Trap"
- "Model Spy"
- "Dangerous Rendezvous"
- "Special Assignment"
- "Place of Angels"
- "Crater 101"
- "Expo 2068"
- "Traitor"
Biographies of the Angels:
- Destiny Angel
- Symphony Angel
- Rhapsody Angel
- Harmony Angel
- Melody Angel
Photo Gallery
Spectrum ID Cards:
- Colonel White
- Captain Blue
- Lieutenant Green
- Captain Magenta
- Dr. Fawn
- Harmony Angel
- Rhapsody Angel
- Captain Scarlet
- Captain Black
- Captain Ochre
- Captain Grey
- Destiny Angel
- Melody Angel
- Symphony Angel
DVD Production Credits

DISC FOUR
Episodes:
- "Flight 104"
- "Noose of Ice"
- "Codename Europa"
- "Flight to Atlantica"
- "Treble Cross"
- "Attack On Cloudbase"
- "The Inquisition"
- "Inferno"
Audio Commentary by co-creator/executive producer Gerry Anderson on "Attack on Cloudbase" (2001)
Vehicle Guides:
- Cloudbase
- SPV
- Saloon Car
- Angel Inceptor
- Maximum Security Vehicle
- Passenger Jet
- Spectrum Helicopter
Production Gallery
DVD Production Credits
DVD-ROM Content:
- Cross section diagrams of vehicles

None

1.33:1

Non-Anamorphic

NTSC

English Dolby Digital 5.1 (except for Attack On Cloudbase)
English Dolby Digital 2.0 Surround (except for Attack On Cloudbase)
English Dolby Digital 2.0 Mono (Attack On Cloudbase only)

Special Case

The episode "Attack On Cloudbase" does not have a 5.1 track (even the episode's menu states this). According to the commentary on menu on disc 4, it was to provide the commentary by Gerry Anderson. In addition, the episode is a PAL-NTSC transfer.

DISC ONE
Episodes:
- "The Mysterons"
- "Winged Assassin"
- "Big Ben Strikes Again"
- "Renegade Rocket"
- "Point 783"
- "Manhunt"
- "Operation Time"
- "White As Snow"
Audio Commentary on "The Mysterons" with co-creator/co-writer/executive producer Gerry Anderson (2001)
"Spotlight On Captain Scarlet: The Directing" 2015 featurette

DISC TWO
Episodes:
- "Seek and Destroy"
- "Spectrum Strikes Back"
- "Avalanche"
- "Shadow of Fear"
- "The Heart of New York"
- "Fire at Rig 15"
- "The Launching"
- "Lunarville 7"
"Spotlight On Captain Scarlet: The Puppets" 2015 featurette

DISC THREE
Episodes:
- "The Trap"
- "Model Spy"
- "Dangerous Rendezvous"
- "Special Assignment"
- "Place of Angels"
- "Crater 101"
- "Expo 2068"
- "Traitor"
"Spotlight On Captain Scarlet: The Writing" 2015 featurette

DISC FOUR
Episodes:
- "Flight 104"
- "Noose of Ice"
- "Codename Europa"
- "Flight to Atlantica"
- "Treble Cross"
- "Attack On Cloudbase"
- "The Inquisition"
- "Inferno"
Audio Commentary on "Attack On Cloudbase" with co-creator/executive producer Gerry Anderson (2001)
Gerry Anderson Interview: Early Career

None

1.33:1

Non-Anamorphic

NTSC

English Dolby Digital 5.1 (except for Attack On Cloudbase)
English Dolby Digital 2.0 Stereo (except for Attack On Cloudbase)
English Dolby Digital 2.0 Mono (Attack On Cloudbase only)

Special Case

Packaged in a 4-disc keep case.
Comes with a slipcase.
The episode "Attack On Cloudbase" is a PAL-NTSC transfer. In addition, it does not have a 5.1 track either (instead, it has an additional 2.0 mono track).
Case incorrectly states the audio as mono (though "Attack On Cloudbase" is presented in mono) and makes no mention of the 5.1 track.

DISC ONE
Episodes:
- "The Mysterons" (27:11)
- "Winged Assassin" (25:01)
- "Big Ben Strikes Again" (25:19)
- "Manhunt" (25:10)
- "Avalanche" (25:00)
- "White as Snow" (24:59)
Audio Commentary with co-creator/co-writer/executive producer Gerry Anderson on "The Mysterons" (2001)
TV 21 Audio Adventure: MA131 - Introducing Captain Scarlet (20:23)
ITC Publicity (7 images, some with zoom function)
TV21 EPs (13 text pages and images)
Character Identities (1 text page each):
- Colonel White
- Captain Scarlet
- Captain Blue
- Captain Black
- Lieutenant Green
- Captain Ochre
- Captain Magenta
- Captain Grey
- Dr. Fawn
- Destiny Angel
- Harmony Angel
- Melody Angel
- Rhapsody Angel
- Symphony Angel

DISC TWO
Episodes:
- "The Trap" (24:53)
- "Operation Time" (25:01)
- "Spectrum Strikes Back" (25:02)
- "Special Assignment" (24:59)
- "The Heart of New York" (25:00)
- "Lunarville 7" (24:58)
TV 21 Adventure: Captain Scarlet and the Mysterons (18:07)
TV Adverts (2 text page preface):
- Lyons Maid Orbit 1 (0:38)
- Lyons Maid Orbit 2 (0:32)
- Kellogg's Sugar Smacks 1 (0:42)
- Kellogg's Sugar Smacks 2 (0:47)
Memorabilia - TV21 Comics (25 text pages and images with zoom function)
Cloud Base and Angel Interceptor (9 text oages followed by a revolving 3D digital model of an Interceptor)

DISC THREE
Episodes:
- "Point 783" (25:08)
- "Model Spy" (24:55)
- "Seek and Destroy" (25:00)
- "Traitor" (25:00)
- "Renegade Rocket" (24:55)
- "Crater 101" (24:59)
TV 21 Audio Adventure 1: Captain Scarlet of SPECTRUM (17:32)
TV 21 Audio Adventure 2: Captain Scarlet is Indestructible (16:46)
Memorabilia: Captain Scarlet Publishing (23 text pages and images with zoom function)
Vehicles:
- SPV: SPECTRUM Pursuit Vehicle (8 text pages and images)
- MSV: Maximum Security Vehicle (4 text pages and images)
- SPJ: SPECTRUM Passenger Jet (4 text pages and images)
- SSC: SPECTRUM Saloon Car (7 text pages and images)
- SPECTRUM Helicopter (4 text pages and images)

DISC FOUR
Episodes:
- "Shadow of Fear" (25:00)
- "Dangerous Rendezvous" (24:59)
- "Fire at Rig 15" (25:00)
- "Treble Cross" (24:58)
- "Flight 104" (25:02)
- "Place of Angels" (24:59)
TV 21 Audio Adventure: Captain Scarlet Vs. Captain Black (19:05)
Captain Scarlet Stills Gallery (17 images)
Memorabilia: Captain Scarlet Merchandise (33 text oages and images with zoom function)
Photo Story: Captain Scarlet on The Golden Shot Appearance (8 text pages and images)

DISC FIVE
Episodes:
- "Noose of Ice" (24:59)
- "Expo 2068" (24:57)
- "The Launching" (25:56)
- "Codename Europa" (24:57)
- "Inferno" (24:59)
- "Flight to Atlantica" (24:56)
- "Attack on Cloudbase" (24:59)
- "The Inquisition" (24:59)
Audio commentary with co-creator/executive producer Gerry Anderson on "Attack on Cloudbase" (2001)
Captain Scarlet Stills Gallery (24 images)

DISC SIX
"Captain Scarlet SIG" 2001 documentary (56:23)
Alternate Opening Titles (prefaced by 4 text pages) (5:14)
ROM:
- Cross section drawings of SPECTRUM vehicles
- Link to the official Captain Scarlet website

English HoH

1.33:1

Non-Anamorphic

PAL

English Dolby Digital 5.1
English Dolby Digital 2.0 Mono

Special Case

This collection is also available in separate volumes, however the 6th disc is exclusive to the box set. The volumes in this boxset have a picture spine; the separate ones don't.