DISC ONE
Episodes: (with Play All option)
- "The Ghost" (43:03)
- "Meet the New Boss" (43:03)
- "Uprising" (42:32)
- "Let Me Stand Next to Your Fire" (43:04)
- "Lockup" (42:15)

DISC TWO
Episodes: (with Play All option)
- "The Good Samaritan" (41:29)
- "Deals with Our Devils" (43:03)
- "The Laws of Inferno Dynamics" (42:31)
- "Broken Promises" (43:04)
- "The Patriot" (42:33)

DISC THREE
Episodes: (with Play All option)
- "Wake Up" (42:54)
- "Hot Potato Soup" (42:59)
- "BOOM" (43:01)
- "The Man Behind the Shield" (42:53)

DISC FOUR
Episodes: (with Play All option)
- "Self Control" (43:04)
- "What If..." (42:57)
- "Identity and Change" (43:02)
- "No Regrets" (43:02)

DISC FIVE
Episodes: (with Play All option)
- "All the Madame's Men" (43:03)
- "Farewell, Cruel World!" (41:30)
- "The Return" (43:04)
- "World's End" (43:02)
"Bloopers of S.H.I.E.L.D." gag reel (4:55)
Deleted Scenes: (with Play All option - 9:14, with 20 second intro)
- "I Said Ice Him" (1:34)
- "Looks Like a Broom Closet" (0:33)
- "Birthday Bombing" (0:53)
- "What's the Labyrinth?" (0:33)
- "You'll Be Many Things" (2:04)
- "Don't Just Beat Them" (0:59)
- "I Just Did" (1:05)
- "Find Him" (0:38)
- "I Admire You" (0:31)

English HoH, German, Japanese

1.78:1

1080p24 AVC MPEG-4

English DTS-HD Master Audio 5.1
German DTS-HD High Resolution 5.1
Japanese Dolby Digital 2.0 stereo

Special Case

Initial pressings in a 5-disc digi-pack housed in a stiff, spot-gloss embossed cardboard slipcase. Subsequent pressings in a 5-disc keep case.